Dalton's Law Calculator Formula

Understand the math behind the dalton's law calculator. Each variable explained with a worked example.

Formulas Used

Total Pressure

p_total = p_a + p_b + p_c

Mole Fraction of Gas A

mole_frac_a = p_a / (p_a + p_b + p_c)

Variables

VariableDescriptionDefault
p_aPartial Pressure of Gas A(atm)0.5
p_bPartial Pressure of Gas B(atm)0.3
p_cPartial Pressure of Gas C (0 if none)(atm)0.2

How It Works

Dalton's Law of Partial Pressures

Formula

P_total = P_A + P_B + P_C + ...

Each gas in a mixture exerts pressure independently as if it alone occupied the container. The partial pressure of each gas equals its mole fraction times the total pressure:

P_i = x_i × P_total

Worked Example

A mixture of N₂ (0.5 atm), O₂ (0.3 atm), and CO₂ (0.2 atm).

p_a = 0.5p_b = 0.3p_c = 0.2
  1. 01P_total = P_A + P_B + P_C
  2. 02P_total = 0.5 + 0.3 + 0.2
  3. 03P_total = 1.0 atm
  4. 04Mole fraction of A = 0.5 / 1.0 = 0.50

Frequently Asked Questions

What is Dalton's Law?

It states that the total pressure of a gas mixture equals the sum of the partial pressures of each individual gas. Each gas behaves independently.

What is a partial pressure?

The partial pressure of a gas in a mixture is the pressure it would exert if it occupied the entire volume alone at the same temperature.

When does this law fail?

Dalton's Law works best for ideal gases. It becomes inaccurate at very high pressures or when gases react with each other.

Ready to run the numbers?

Open Dalton's Law Calculator