Free Half-Life Calculator (First Order)

Calculate the half-life of a first-order reaction from its rate constant, or find the rate constant from a known half-life.

1/s

Half-Life (t½)

13.8629 s

Half-Life0.2310 min

Half-Life (t½) vs Rate Constant (k)

First-Order Half-Life

For a first-order reaction, the half-life is the time required for the concentration to decrease to half of its initial value. Uniquely for first-order kinetics, the half-life is independent of initial concentration.

Formula

t½ = ln(2) / k = 0.693 / k

where k is the first-order rate constant. This formula applies to radioactive decay, drug metabolism, and many chemical decomposition reactions.

Example Calculation

A first-order reaction with rate constant k = 0.05 s⁻¹.

  1. 01t½ = ln(2) / 0.05
  2. 02t½ = 0.6931 / 0.05 = 13.86 s
  3. 03In minutes: 13.86 / 60 = 0.231 min

Frequently Asked Questions

Learn More

Understanding Molarity

Learn what molarity is, how to calculate it, and why it matters in chemistry. Covers moles, liters, dilution, and step-by-step examples for preparing solutions.

Related Calculators