Free Degree of Unsaturation Calculator

Calculate the degree of unsaturation (index of hydrogen deficiency) from a molecular formula containing C, H, N, and halogens.

Degrees of Unsaturation

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Degrees of Unsaturation vs Number of Carbons (C)

Degree of Unsaturation (Index of Hydrogen Deficiency)

The degree of unsaturation tells how many rings and/or double bonds are in a molecule. Each ring or double bond reduces the hydrogen count by 2 relative to the fully saturated formula.

Formula

DoU = (2C + 2 + N - H - X) / 2

where C = carbons, H = hydrogens, N = nitrogens, X = halogens. Oxygen and sulfur are not included because they do not change the hydrogen count. A DoU of 4 for a C6 compound suggests a benzene ring.

Example Calculation

Calculate the degree of unsaturation for benzene (C6H6).

  1. 01DoU = (2 × 6 + 2 + 0 - 6 - 0) / 2
  2. 02DoU = (12 + 2 - 6) / 2 = 8 / 2 = 4
  3. 03Benzene has 3 double bonds + 1 ring = 4 DoU

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